Distonic ion: Difference between revisions
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A radical cation or anion in which the charge site and the spin charge (unpaired electron) cannot be both formally located in the same atom or group of atoms, as opposed to the electronic configuration of conventional ions for which both sites can be placed in the same atom. For instance, | {{DefName|A radical cation or anion in which the charge site and the spin charge (unpaired electron) cannot be both formally located in the same atom or group of atoms, as opposed to the electronic configuration of conventional ions for which both sites can be placed in the same atom. For instance, ?????????????????????CH<sub>2</sub>-OH<sub>2</sub><sup>+</sup> is a distonic ion whereas for its conventional isomer, that is, the radical cation of methanol, CH<sub>3</sub>OH<sup>+?????????????????????</sup>, the charge and spin sites are formally located at the O atom. }} | ||
[[Category:Ions]] | [[Category:Ions]] | ||
Revision as of 23:43, 23 February 2005
| DRAFT DEFINITION |
| Distonic ion |
|---|
| A radical cation or anion in which the charge site and the spin charge (unpaired electron) cannot be both formally located in the same atom or group of atoms, as opposed to the electronic configuration of conventional ions for which both sites can be placed in the same atom. For instance, ?????????????????????CH2-OH2+ is a distonic ion whereas for its conventional isomer, that is, the radical cation of methanol, CH3OH+?????????????????????, the charge and spin sites are formally located at the O atom. |
| Considered between 2004 and 2006 but not included in the 2006 PAC submission |
| This is an unofficial draft definition presented for information and comment. |
