McLafferty rearrangement: Difference between revisions
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== External Links == | == External Links == | ||
[http://www.iupac.org/goldbook/M03772.pdf IUPAC Gold Book Entry (PDF)] | *[http://www.iupac.org/goldbook/M03772.pdf IUPAC Gold Book Entry (PDF)] | ||
[http://themerckindex.cambridgesoft.com/TheMerckIndex/NameReactions/onr240.htm CambridgeSoft Link] | *[http://themerckindex.cambridgesoft.com/TheMerckIndex/NameReactions/onr240.htm CambridgeSoft Link] | ||
:with figure:http://themerckindex.cambridgesoft.com/TheMerckIndex/NameReactions/3795307.gif | :with figure:http://themerckindex.cambridgesoft.com/TheMerckIndex/NameReactions/3795307.gif | ||
*[http://masspec.scripps.edu/information/history/names/detail.html?id=12 Fred McLafferty Biography (Scripps)] | |||
[[Category:Reactions]] | [[Category:Reactions]] | ||
Revision as of 12:46, 1 December 2005
| DRAFT DEFINITION |
| McLafferty rearrangement |
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β Cleavage with concomitant specific transfer of a gamma-hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or an ionic mechanism, and irrespective of the position of the charge. |
| Considered between 2004 and 2006 but not included in the 2006 PAC submission |
| This is an unofficial draft definition presented for information and comment. |
Orange Book Entry
This is an example of a rearrangement reaction and is defined as β - cleavage with concomitant specific transfer of a γ - hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or by an ionic mechanism and irrespective of with which fragment the charge stays.
Gold Book Entry
β-Cleavage with concomitant specific transfer of a γ-hydrogen atom in a six-membered transition state in mono-unsaturated systems, irrespective of whether the rearrangement is formulated by a radical or an ionic mechanism, and irrespective of the position of the charge.
