Resolving power (in mass spectrometry): Difference between revisions

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=Other versions=
=Other versions=
{{Def2|
In a [[mass spectrum]], the observed mass divided by the difference between two masses that can be separated:  '''m'''/Δ'''m'''. The method by which Δ'''m''' was obtained and the mass at which the measurement was made should be reported.
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PAC, 1978, 50, 65 ([[Recommendations for symbolism and nomenclature for mass spectroscopy]]) on page 72
PAC, 1978, 50, 65 ([[Recommendations for symbolism and nomenclature for mass spectroscopy]]) on page 72
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== See also ==
*[[Resolution (mass spectrometry)]]
== External links ==
*[[Reference:Marshall 2002]] gives the following definitions:
:'''Mass peak width (&#916;m<sub>50%</sub>)'''
::Full width of mass spectral peak at half-maximum peak height
:'''Mass resolving power (m/&#916;m<sub>50%</sub>)'''
::A well-isolated single mass spectral peak
:'''Mass resolution (m<sub>2</sub> m<sub>1</sub> in Da, or (m<sub>2</sub> m<sub>1</sub>)/m<sub>1</sub> in ppm)'''
::The smallest mass difference between equal magnitude peaks such that the valley between them is a specified fraction of either peak height
:'''Mass precision'''
::Root-mean-square deviation in a large number of repeated measurements
:'''Mass accuracy'''
::Difference between measured and actual mass
:'''Mass defect'''
::Difference between exact and nominal mass
* [http://www.jeol.com/ms/docs/resolution.html JEOL Resolution Tutorial]


[[Category:Mass]]
[[Category:Mass]]

Revision as of 17:36, 11 October 2012


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Other versions

Orange Book

ORANGE BOOK DEFINITION

IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023)

Resolving power (in mass spectrometry)

The ability to distinguish between ions differing in the quotient mass/charge by a small increment. It may be characterized by giving the peak width, measured in mass units, expressed as a function of mass, for at least two points on the peak, specifically for 50% and for 5% of the maximum peak height.

IUPAC 1997 Orange Book Chapter 12
Index of Orange Book Terms


Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Resolving power (in mass spectrometry)

Resolving power (mass spectrometry)

http://goldbook.iupac.org/R05321.html

The ability to distinguish between ions differing in the quotient mass/charge by a small increment. It may be characterized by giving the peak width, measured in mass units, expressed as a function of mass, for at least two points on the peak, specifically at fifty percent and at five percent of the maximum peak height.

mass resolving power

http://goldbook.iupac.org/M03730.html

Commonly and also acceptably defined in terms of the overlap (or 'valley') between two peaks. Thus for two peaks of equal height, masses and , when there is overlap between the two peaks to a stated percentage of either peak height (10% is recommended), then the resolving power is defined as . The percentage overlap (or 'valley') concerned must always be stated.

Source: PAC, 1978, 50, 65 (Recommendations for symbolism and nomenclature for mass spectroscopy) on page 72

IUPAC Gold Book
Index of Gold Book Terms
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