Sensitivity: Difference between revisions
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== Orange Book entry == | == Orange Book entry == | ||
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This is the observed change in ion curent per unit mass of sample flow through the [[Ion Source]] and is measured in coulomb per microgram, C | This is the observed change in ion curent per unit mass of sample flow through the [[Ion Source]] and is measured in coulomb per microgram, C ?????g<sup>-1</sup>. An alternative measure of sensitivity, more suitable for gases, is the observed change in partial pressure of the sample in the [[Ion Source]], expressed in ampere per pascal, A/Pa. | ||
See also [[Orange Book]] Chapter} 18.4.3.2. | See also [[Orange Book]] Chapter} 18.4.3.2. | ||
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== Gold Book Entry == | == Gold Book Entry == | ||
Revision as of 12:07, 12 July 2009
| DRAFT DEFINITION |
| Sensitivity |
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Sensitivity is ratio of change in ion current to the sample concentration. It is the slope of the graph for the sample concentration versus the measured signal. |
| Considered between 2004 and 2006 but not included in the 2006 PAC submission |
| This is an unofficial draft definition presented for information and comment. |
Orange Book entry
Orange Book
| ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
| Sensitivity |
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This is the observed change in ion curent per unit mass of sample flow through the Ion Source and is measured in coulomb per microgram, C ?????g-1. An alternative measure of sensitivity, more suitable for gases, is the observed change in partial pressure of the sample in the Ion Source, expressed in ampere per pascal, A/Pa. See also Orange Book Chapter} 18.4.3.2. |
| IUPAC 1997 Orange Book Chapter 12 |
| Index of Orange Book Terms |
Gold Book Entry
Two different measures of sensitivity are recommended. The first, which is suitable for relatively involatile materials as well as gases, depends upon the observed change in ion current for a particular amount or change of flow rate of sample though the ion source. A second method of stating sensitivity, that is most suitable for gases, depends upon the change of ion current related to the change of partial pressure of the sample in the ion source.
It is important that the relevant experimental conditions corresponding to sensitivity measurement should always be stated. These include in a typical case details of the instrument type, bombarding electron current, slit dimensions, angular collimation, gain of the multiplier detector, scan speed and whether the measured signal corresponds to a single mass peak or to the ion beam integrated over all masses. Some indication of the time involved in the determination should be given, e.g. counting time or band width. The sensitivity should be differentiated from the detection limit.
