Charge-transfer reaction (in mass spectrometry): Difference between revisions
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== [[Orange Book]] Entry == | == [[Orange Book]] Entry == | ||
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An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M<sup>2+,</sup> M<sup>+</sup> and M<sup>-</sup> with a neutral species X are categorized in terms of the above definitions as follows: | An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M<sup>2+,</sup> M<sup>+</sup> and M<sup>-</sup> with a neutral species X are categorized in terms of the above definitions as follows: | ||
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These are all ion/neutral species reactions and also [[Charge Permutation Reaction|charge permutation reactions]]. | These are all ion/neutral species reactions and also [[Charge Permutation Reaction|charge permutation reactions]]. | ||
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== Related Terms == | == Related Terms == | ||
Revision as of 22:02, 9 July 2009
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Orange Book Entry
Orange Book
| ORANGE BOOK DEFINITION
IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) |
| Charge-transfer reaction (in mass spectrometry) |
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An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M2+, M+ and M- with a neutral species X are categorized in terms of the above definitions as follows: M2+ + X → M+ + X+ (Partial charge transfer) M+ + X → M2+ + X + e (Charge stripping) M- + X → M+ + X + 2e (Charge stripping & charge inversion) These are all ion/neutral species reactions and also charge permutation reactions. |
| IUPAC 1997 Orange Book Chapter 12 |
| Index of Orange Book Terms |
