Charge-transfer reaction (in mass spectrometry): Difference between revisions
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M2<sup>+</sup> + X ??????????????????????????????? M+ + X<sup>+</sup> (Partial charge transfer) | M2<sup>+</sup> + X ??????????????????????????????? M+ + X<sup>+</sup> (Partial charge transfer) | ||
M<sup>+</sup> + X ??????????????????????????????? | M<sup>+</sup> + X ??????????????????????????????? M<sub>2</sub><sup>+</sup> + X + e ([[Charge Stripping Reaction|Charge stripping]]) | ||
M<sup>-</sup> + X ??????????????????????????????? M<sup>+</sup> X + 2e ([[Charge Stripping Reaction|Charge stripping]] & [[Charge Inversion Reaction|charge inversion]]) | M<sup>-</sup> + X ??????????????????????????????? M<sup>+</sup> X + 2e ([[Charge Stripping Reaction|Charge stripping]] & [[Charge Inversion Reaction|charge inversion]]) | ||
These are all ion/neutral species reactions and also [[Charge Permutation Reaction|charge permutation reactions]]. | These are all ion/neutral species reactions and also [[Charge Permutation Reaction|charge permutation reactions]]. | ||
[[Category:Reactions]] | |||
Revision as of 23:17, 21 January 2005
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Orange Book Entry
An ion/neutral species reaction in which the total charge on the reactant ion is transferred initially to the reactant neutral species so that the reactant ion becomes a neutral entity. Some of the possible reactions of ions M2+, M+ and M- with a neutral species X are categorized in terms of the above definitions as follows:
M2+ + X ??????????????????????????????? M+ + X+ (Partial charge transfer)
M+ + X ??????????????????????????????? M2+ + X + e (Charge stripping)
M- + X ??????????????????????????????? M+ X + 2e (Charge stripping & charge inversion)
These are all ion/neutral species reactions and also charge permutation reactions.
