Isotopolog ion: Difference between revisions

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{{Def2|
Ions that differ only in the isotopic composition of one or more of its constituent atoms. For example CH<sub>4</sub><sup>+.</sup> and CH<sub>3</sub>D<sup>+.</sup> or <sup>10</sup>BF<sub>3</sub> and <sup>11</sup>BF<sub>3</sub>. The term isotopologue is a shortening of isotopic homologue.
Ions that differ only in the isotopic composition of one or more of its constituent atoms. For example CH<sub>4</sub><sup>+.</sup> and CH<sub>3</sub>D<sup>+.</sup> or <sup>10</sup>BF<sub>3</sub> and <sup>11</sup>BF<sub>3</sub>. The term isotopologue is a shortening of isotopic homologue.
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{{rev5|
Ions that differ only in the isotopic composition of one or more of the constituent atoms. For example, CH4+????????? and CH3D+????????? or 10BF3 and 11BF3, or the ions forming an isotope cluster corresponding to the natural abundance of the constituent atoms.
Note:  isotopolog is an abbreviation of isotopic homolog.
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#O. D. Sparkman. Mass Spec Desk Reference. Global View Publishing, Pittsburgh (2006).
#[[Gold Book]]
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{{gold|
'''isotopologue'''
A molecular entity that differs only in isotopic composition (number of isotopic substitutions), e.g. CH4, CH3D, CH2D2.
Source:
PAC, 1994, 66, 1077 ([[Glossary of terms used in physical organic chemistry]] (IUPAC Recommendations 1994)) on page 1132
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Gold Book

GOLD BOOK DEFINITION

IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997).

Isotopolog ion

isotopologue

A molecular entity that differs only in isotopic composition (number of isotopic substitutions), e.g. CH4, CH3D, CH2D2.

Source: PAC, 1994, 66, 1077 (Glossary of terms used in physical organic chemistry (IUPAC Recommendations 1994)) on page 1132

IUPAC Gold Book
Index of Gold Book Terms


See also