Metastable ion: Difference between revisions
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| |def=[[Ion]] formed with internal energy higher than the threshold for dissociation but with a lifetime great enough to allow it to exit the [[ion source]] and enter the [[mass analyzer]] region where it dissociates before detection. | |||
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| |ref={{obgb}} | |||
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| <!-- Orange Book --> | |||
| {{orange| | |||
| An ion which is formed with sufficient excitation to dissociate spontaneously during its flight from the ion source to the detector. | |||
| }} | |||
| <!-- Gold Book --> | |||
| {{gold| | |||
| http://goldbook.iupac.org/M03874.html | |||
| An ion which is formed with sufficient excitation to dissociate spontaneously during its flight from the ion source to the detector. | An ion which is formed with sufficient excitation to dissociate spontaneously during its flight from the ion source to the detector. | ||
| '''Source''': | |||
| PAC, 1991, 63, 1541 ([[Recommendations for nomenclature and symbolism for mass spectroscopy]] (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1549 | |||
| }} | |||
| [[ | [[Category:Ions]] | ||
| [[Category:Reactions]][[Category:Fragmentation]] | |||
| [[Category:Orange Book term]] | |||
| {{DEFAULTSORT:Metastable Ion}} | |||
Latest revision as of 11:06, 8 August 2025
| IUPAC RECOMMENDATIONS 2013 | 
| Metastable ion | 
|---|
| Ion formed with internal energy higher than the threshold for dissociation but with a lifetime great enough to allow it to exit the ion source and enter the mass analyzer region where it dissociates before detection. | 
| Related Term(s): | 
| Reference(s): IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979. Compiled by J. Inczdy, T. Lengyel, A. M. Ure. Blackwell Scientific Publications, Oxford (1997). On-line corrected version: http://www.iupac.org /publications/analytical compendium (2000). IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). XML on-line corrected version: http://goldbook.iupac.org (2006-) created by M. Nic, J. Jirat, B. Kosata; updates compiled by A. Jenkins. | 
| From Definitions of Terms Relating to Mass Spectrometry (IUPAC Recommendations 2013); DOI: 10.1351/PAC-REC-06-04-06 © IUPAC 2013. | 
Orange Book
| ORANGE BOOK DEFINITION IUPAC. Analytical Division. Compendium of Analytical Nomenclature (the Orange Book). Definitive Rules, 1979 (see also Orange Book 2023) | 
| Metastable ion | 
|---|
| An ion which is formed with sufficient excitation to dissociate spontaneously during its flight from the ion source to the detector. | 
| IUPAC 1997 Orange Book Chapter 12 | 
| Index of Orange Book Terms | 
Gold Book
| GOLD BOOK DEFINITION IUPAC. Compendium of Chemical Terminology, 2nd ed. (the Gold Book). Compiled by A. D. McNaught and A.Wilkinson. Blackwell Scientific Publications, Oxford (1997). | 
| Metastable ion | 
|---|
| http://goldbook.iupac.org/M03874.html An ion which is formed with sufficient excitation to dissociate spontaneously during its flight from the ion source to the detector. Source: PAC, 1991, 63, 1541 (Recommendations for nomenclature and symbolism for mass spectroscopy (including an appendix of terms used in vacuum technology). (Recommendations 1991)) on page 1549 | 
| IUPAC Gold Book | 
| Index of Gold Book Terms | 
